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Polyphosphoric Acid (PPA)

Clear viscous liquid (105–118% H₃PO₄ eq.) for pharmaceutical cyclizations & asphalt modification.

CAS 8017-16-1 UN 3264 · Class 8 Grade 105–118% H₃PO₄ eq.

Product Overview

The Specialized Reagent for Intramolecular Cyclization

Polyphosphoric Acid (PPA) is a clear, viscous liquid composed of condensed polymeric phosphoric acid species. It is expressed as having a strength of 105–118% H₃PO₄ equivalent (~76–85% P₂O₅ content).

High-purity Polyphosphoric Acid PPA manufactured at Darshan Fine Chem Private Limited, Ankleshwar Gujarat India PPA

Technical Specifications

Physical & Chemical Properties

Verified by titrimetric analysis and density control.

CAS Number 8017-16-1
UN / Hazard Class UN 3264 · Class 8 (PG III)
Appearance Clear to pale yellow viscous liquid
H₃PO₄ Equivalent 105 – 118%
P₂O₅ Equivalent ~76 – 85%
Viscosity Highly viscous at 25 °C (drops above 60 °C)
Solubility Miscible with water (hydrolyses slowly → H₃PO₄)

Packaging & Supply

Flexible Supply Configurations

Supplied in heavy-duty HDPE containers and road tankers across India and export markets.

50 kg HDPE Carboys 250 kg HDPE Drums Tanker Loads (dedicated stainless steel)

Corrosive Liquid: PPA is UN 3264, Class 8. Highly viscous; handles easily when warmed gently. Always use acid-resistant PPE and ensure dry equipment to prevent exothermic hydrolysis.

Industrial Applications

Where PPA Powers Global Chemistry

Key applications in pharmaceutical heterocycles, asphalt modification, and surfactants.

Pharma Cyclization

Reagent of choice for intramolecular dehydrations and cyclizations forming benzimidazoles, benzothiazoles, indanones, and tetrahydroisoquinolines in API synthesis.

Bitumen Modification

Used as an asphalt additive to enhance high-temperature viscosity and rutting resistance in heavy-traffic highway road construction.

Surfactant Esters

Reacts with alcohols to produce alkyl phosphate esters used as anti-static agents, wetting agents, and emulsifiers in industrial detergents.

Dye Condensation

Serves as a condensation medium and acid catalyst in anthraquinone and phthalocyanine dye and pigment manufacturing.

Beckmann Rearrangement

Catalyzes the conversion of oximes to amides, a critical reaction step in specialty polymer and nylon chemical processing.

Why Source from Us

Darshan Fine Chem Private Limited Quality Promise

Exact 105–118% Grade

Consistently high P₂O₅ concentration ensures maximum cyclization power and batch yield.

Pharma Grade QC

Controlled metal impurity levels for sensitive active pharmaceutical ingredient manufacturing.

COA & SDS Included

Batch Certificate of Analysis and SDS provided with every consignment.

Bulk Delivery

Available in drums and carboys with fast dispatch from Sayakha GIDC, Gujarat.

FAQs

Frequently Asked Questions — Polyphosphoric Acid

Pure orthophosphoric acid is 100%. Above 100% indicates condensed polyphosphoric species with higher phosphorus content (~76–85% P₂O₅), providing strong dehydrating and cyclizing power.
PPA acts as both catalyst and dehydrating solvent, offering milder conditions and higher selectivity while avoiding sulfonation side-reactions caused by H₂SO₄.
PPA is viscous at room temperature. Warming to 60–80°C significantly reduces viscosity for easy pumping and transfer.
Yes. PPA is widely used to modify road bitumen to improve high-temperature rutting resistance and extend road lifespan.
We supply Polyphosphoric Acid in 50 kg HDPE Carboys, 250 kg HDPE Drums, and Tanker Loads.

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